Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 35: Issue 4
Solid state reactivity of organic compounds with inorganic compounds. IV synthesis and thermal decomposition of uranium oxinate in the solid state
Authors:
P. S. Bassi Department of Chemistry Guru Nanak dev University 143005 Amritsar India

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G. S. Chopra Department of Chemistry Guru Nanak dev University 143005 Amritsar India

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K. Kaur Department of Chemistry Guru Nanak dev University 143005 Amritsar India

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Pages:
1213–1221
Online Publication Date:
24 Jul 2005
Publication Date:
01 Jul 1989
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01913040
Restricted access

8-hydroxyquinoline (oxine) and uranyl acetate react in the solid state in 1∶3 stoichiometry to give UO2(C9H6NO)2·C9H6NOH. This reaction is diffusion controlled with an activation energy of 44.4 kJ mol−1. The reaction occurs by the surface migration of 8-hydroxyquinoline, which penetrates the product lattice to react with uranyl acetate. The isothermal decomposition of the solution phase product UO2Q2·HQ (Q=C9H6NO) obeys the Prout-Tompkins equation with an energy of activation of 53.3 kJ mol−1.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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