Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 36: Issue 4
The study of the thermal dissociation processes of compounds of the type MoO2(C6H5CONHO)2.nA
Authors:
V. A. Logvinenko Institute of Inorganic Chemistry Siberian Department of The Academy of Sciences of The U.S.S.R. Novosibirsk USSR

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G. V. Gavrilova Institute of Inorganic Chemistry Siberian Department of The Academy of Sciences of The U.S.S.R. Novosibirsk USSR

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L. K. Kim Institute of Chemistry The Academy of Sciences of the Uz.S.S.R. Tashkent USSR

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Kh. T. Sharipov Institute of Chemistry The Academy of Sciences of the Uz.S.S.R. Tashkent USSR

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T. A. Azizov Institute of Chemistry The Academy of Sciences of the Uz.S.S.R. Tashkent USSR

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Pages:
1393–1399
Online Publication Date:
25 Jul 2005
Publication Date:
01 Jul 1990
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01914062
Restricted access

Thermal dissociation processes of compounds with the composition MoO2(C6H5CONHO)2.nA (A-polar organic solvent: alcohols, aldehydes, ketones, organic acids) were investigated. Kinetics of dissociation was studied in a flow reactor, the values of activation energy and preexponential factor were calculated. The influence of a solvent nature, of the length of included molecules and of the type of crystalline lattice was studied. The sequence of kinetic stability was obtained. It corresponds to the sequence of solvent activity with respect to H-binding up with the complex. For the series of alcohols nonmonotonous dependence of kinetic parameters on the length of chain (with the division into two groups: with even and oddn) was obtained. For all the compounds studied a compensation relationship is observed (lgA=aE+b).

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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