Authors:
N. Koga Chemistry Laboratory, Faculty of School Education Hiroshima University Shinonome, Minami-Ku 734 Hiroshima Japan

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H. Tanaka Chemistry Laboratory, Faculty of School Education Hiroshima University Shinonome, Minami-Ku 734 Hiroshima Japan

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Two causes for the kinetic compensation effect (KCE) were recognized for a given solidstate reaction at various heating rates. One is due to any change in the range of reaction. This KCE is quantitative and meaningful, provided thatF(α) remains constant under the given conditions. The other is due to misestimation of the appropriate rate law, which in turn leads to a superficial KCE. It was also shown that the existence of an isokinetic point does not necessarily imply the occurrence of a meaningful KCE.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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