Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 38: Issue 4
Isothermal bulk polymerization ofp-alkylaryl methacrylates by DSC
Authors:
J. M. Filipovic Faculty of Technology and Metallurgy University of Beograd Karnegijeva 4 11000 Beograd Yugoslavia

Search for other papers by J. M. Filipovic in
Current site
Google Scholar
PubMed Close
,
D. M. Petrovic-Dakov Faculty of Technology and Metallurgy University of Beograd Karnegijeva 4 11000 Beograd Yugoslavia

Search for other papers by D. M. Petrovic-Dakov in
Current site
Google Scholar
PubMed Close
,
Lj. P. Vrhovac Faculty of Technology and Metallurgy University of Beograd Karnegijeva 4 11000 Beograd Yugoslavia

Search for other papers by Lj. P. Vrhovac in
Current site
Google Scholar
PubMed Close
, and
J. S. Velickovic Faculty of Technology and Metallurgy University of Beograd Karnegijeva 4 11000 Beograd Yugoslavia

Search for other papers by J. S. Velickovic in
Current site
Google Scholar
PubMed Close
Pages:
709–713
Online Publication Date:
02 Aug 2005
Publication Date:
01 Apr 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01979400
Keywords:
enthalpy of polymerization; free radical polymerization; kinetics; p-alkylphenyl methacrylates
Restricted access

The course and kinetics of free radical polymerization in bulk ofp-alkylphenyl methacrylates with AIBN initiator were studied by DSC, in the temperature range 348–373 K. The enthalpy of polymerization, the residual monomer content, as well as the overall reaction rate constants and the activation energies were determined. The similar values of the overall rate constants indicate that the relatively small alkyl substituents inp-position of the phenyl ring affect the polymerization rate to a very small, if any, extent.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Mar 2024 4 0 0
Apr 2024 2 0 0
May 2024 0 0 0
Jun 2024 3 0 0
Jul 2024 3 0 0
Aug 2024 5 0 0
Sep 2024 6 0 0