Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 38: Issue 4
Calorimetric investigation of thermodynamic properties and ions rotation of some perbromates
Authors:
V. B. Lazarev The Kurnakov Institute of General and Inorganic Chemistry Leninsky Prospect 31 117907 Moscow USSR

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K. S. Gavrichev The Kurnakov Institute of General and Inorganic Chemistry Leninsky Prospect 31 117907 Moscow USSR

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V. E. Gorbunov The Kurnakov Institute of General and Inorganic Chemistry Leninsky Prospect 31 117907 Moscow USSR

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Pages:
865–872
Online Publication Date:
02 Aug 2005
Publication Date:
01 Apr 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01979418
Keywords:
adiabatic calorimetry; heat capacity of perbromates
Restricted access

Low temperature heat capacity of ammonium, rubidium and cesium perbromates has been studied by method of adiabatic calorimetry. Anomaly of the heat capacity of cesium perbromate has been found, which corresponds to a structural phase transition. The separation of heat capacity into components has been carried out by the additive scheme. The torsion oscillation of BrO4− anions in solid perbromates at low temperatures has been found. Ammonium ions retardedly rotate aroundC2 axes in the crystal lattice of NH4BrO4.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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