Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 38: Issue 5
Thermodynamics of propanal polymerization and thermodynamic functions of polypropanal from 0 K to 370 K at standard pressure
Authors:
B. V. LebedevChemistry Institute N. I. Lobachevsky State University Nizhny Novgorod Russia

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V. G. Vasil'yevChemistry Institute N. I. Lobachevsky State University Nizhny Novgorod Russia

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N. N. NovosyolovaChemistry Institute N. I. Lobachevsky State University Nizhny Novgorod Russia

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Pages:
1299–1309
Online Publication Date:
02 Aug 2005
Publication Date:
01 May 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01979189
Keywords:
polymerization; propanal; thermodynamic parameters
Restricted access

The heat capacityCpo of polypropanal was studied in a vacuum adiabatic calorimeter between 11 and 330 K, and in an ADKTTM automatic differential calorimeter from 320 to 370 K. The thermodynamic parameters of melting and glass transition of polypropanal were also determined. From the results, the thermodynamic functions of the polymer were calculated in the range 0 K to 360 K. The enthalpy of depolymerization of polypropanal to the starting monomer was measured in a DAK-1-1 differential automatic microcalorimeter. From the results of this study and literature data on the thermodynamic properties of propanal., the enthalpy, entropy and Gibbs function of bulk polymerization of propanal were estimated from 0 K to 330 K. Ceiling limiting temperatures of transitions of the liquid monomer to crystalline and high-elasticity polymer were determined.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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