Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 38: Issue 8
Excess enthalpies of cycloether + methyl methylthiomethyl sulfoxide or dimethyl sulfoxide at 298.15 K
Authors:
T. Kimura Department of Chemistry, Faculty of Science and Technology Kinki University Kowakae 577 Higashi-Osaka Japan

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S. Tahara Department of Chemistry, Faculty of Science and Technology Kinki University Kowakae 577 Higashi-Osaka Japan

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S. Takagi Department of Chemistry, Faculty of Science and Technology Kinki University Kowakae 577 Higashi-Osaka Japan

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Pages:
1911–1920
Online Publication Date:
02 Aug 2005
Publication Date:
01 Aug 1992
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01974685
Keywords:
binary mixtures; excess enthalpies
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Excess enthalpies of ten binary mixtures of each of methyl methylthiomethyl sulfoxide (MMTSO) and dimethyl sulfoxide (DMSO) with one of the cycloethers (oxane, 1,3- and 1,4-dioxanes, oxolane and 1,3-dioxolane) have been determined at 298.15 K. All the mixtures show positive excess enthalpies over the whole composition range. Excess enthalpies of the cycloether + MMTSO or DMSO decrease with increasing number of oxygen atoms in the cycloether molecules, except for oxolane + MMTSO. Excess enthalpies of MMTSO + cycloethers are smaller than those of DMSO + cycloethers for the same cycloether except for the 1,3-dioxolane mixtures.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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