Authors:
J. Liu Chinese Academy of Sciences Dalian Institute of Chemical Physics 116011 Dalian P.R. China

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J. Shen Chinese Academy of Sciences Dalian Institute of Chemical Physics 116011 Dalian P.R. China

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X. Gao Chinese Academy of Sciences Dalian Institute of Chemical Physics 116011 Dalian P.R. China

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L. Lin Chinese Academy of Sciences Dalian Institute of Chemical Physics 116011 Dalian P.R. China

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Abstract  

Carburization and coke deposition of unsupported and carbon-supported Fe, Mo and Fe−Mo catalysts in syngas have been studied using thermogravimetry. Compositions of the carbides formed are evaluated on the basis of the amount of metals in the catalysts and amount of carbon deposited during carburization. It is shown that carburization temperature and the nature of the carbides formed (Fe5C2 and Fe2C for iron and Mo2C for molybdenum) depend on the metals but are influenced by the support and metal loading. Coke deposition on these catalysts takes place as soon as carburization is complete.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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