Authors:
S. Békássy Technical University of Budapest Department of organic chemical technology H-1521 Budapest Hungary

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T. Cseri Technical University of Budapest Department of organic chemical technology H-1521 Budapest Hungary

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G. Kenessey Technical University of Budapest Department of Inorganic Chemistry H-1521 Budapest Hungary

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G. Pokol Technical University of Budapest Department of General and Analytical chemistry H-1521 Budapest Hungary

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K. Tomor Technical University of Budapest Department of General and Analytical chemistry H-1521 Budapest Hungary

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G. Liptay Technical University of Budapest Department of Inorganic Chemistry H-1521 Budapest Hungary

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Abstract  

Montmorillonite-supported iron(III) nitrate and copper(II) nitrate reagents, and other supported metal nitrates prepared in the same way, were investigated by thermal and X-ray powder diffraction methods. The metal nitrates are present on the support in the form of crystalline hydrate and not as acetone solvate as supposed earlier. Thermal decomposition of metal nitrates that are active in model reactions proceeds in a different way from that of the practically inactive nitrates. In the former case, water release and nitrate decomposition itself are simultaneous process. These and other results contributed to determination of suitable reaction conditions for the montmorillonite-supported reagents.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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