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  • 1 Helsinki University of Technology Laboratory of Inorganic and Analytical Chemistry Sf-02150 Espoo Finland
  • | 2 Technical University of Budapest Department of Inorganic Chemistry H-1521 Budapest Hungary
  • | 3 Technical University of Budapest Department of Inorganic Chemistry Hungary
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Abstract  

The thermal decomposition of some new primary aliphatic amine RNH2 (R=methyl-, ethyl-,n-propyl,i-propyl,n-butyl-,i-butyl-,n-amyl-,i-amyl-, cyclohexyl-andi-allyl-) complexes with cadmium(II) chloride, prepared by solid-gas phase chemisorption, have been investigated by simultaneous TG-DTG-DTA. The enthalpy changes during the degradation were followed by DSC. The course of the thermal decomposition is described in detail. The thermal properties observed were compared to the more recently reported nickel(II) analogues. The changes in thermal parameters in the series of cadmium(II) chloride aliphatic amine complexes are discussed on the basis of the inductive releasing effect of the aliphatic chain and the steric hindrance of the ligands.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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