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  • 1 Inorganic Chemistry, University GH Kassel Germany
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Abstract  

The ternary system CsCl−NaCl−LaCl3 was investigated by means of differential thermal analysis and X-ray powder diffraction analysis. There exists one congruently melting compound, Cs2NaLaCl6, crystallizing with the cubic elpasolite structure. No quasi-binary section exists for the whole system, however three binaries range from the ternary compound Cs2NaLaCl6 to NaCl, CsLa2Cl7 and Cs3LaCl6 resp., dividing the system in three areas of composition: one triangle, Cs3LaCl6−Cs2NaLaCl6−CsLa2Cl7, containing additionally a compound Cs2LaCl5 below 510°C, and the two areas CsCl−NaCl−Cs2NaLaCl6−Cs3LaCl6 and Cs2NaLaCl6−NaCl−LaCl3−CsLa2Cl7, containing a mixed crystal range between LaCl3 and Na3La5Cl18. These areas could be further divided in five triangles, so that the whole system contains six Alkemade triangles.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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