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  • 1 Slovak Technical University Department of Inorganic Chemistry Radlinského 9 812 37 Bratislava Slovakia
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Abstract  

The thermal dehydration of pentacoordinate complexes [Cu(maleinate)(H2O)] (I), [Cu2(citrate) (H2O)2] (II) and [Cu(phenoxyacetate)2(H2O3] (III) was investigated and correlated with the structural changes occurring during the dehydration. It was found that the activation parameters of the reactions do not follow the lengths of the split Cu−OH2 bonds. The lowestEa and lgA values were found for compound I, the highest ones for compound III. The most expressive changes of the anionic ligand binding mode take place during the dehydration of this compound.

Manuscript Submission: HERE

  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)