Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 42: Issue 6
Thermal decomposition of Me3SnO2PCl2, Me2Sn(O2PCl2)2 and Ph3SnO2PCl2
Authors: A. Shihada 1 , A. Said 1 , and R. Al Qasmi 1
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  • 1 United Arab Emirates University Department of Chemistry, College of Science P.O. Box 17551 UAE Al-Ain P.O. Box 17551 UAE Al-Ain
  • 2 Assiut University Chemistry Department, Faculty of Science Assiut Egypt Assiut Egypt
DOI:
https://doi.org/10.1007/bf02546939
Page Count:
1313–1318
Publication Date:
01 Dec 1994
Online Publication Date:
09 Jan 2007
Article Category:
Research Article
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Abstract  

TG and DTA studies on Me3SnO2PCl2, Me2Sn(O2PCl2)2 and Ph3SnO2PCl2 were carried out under dynamic argon atmosphere. The results show that the decomposition proceeds in different stages leading to the formation of Sn3(PO4)2 as a stable product. This compound was characterized by IR spectroscopy. Decomposition schemes involving reductive elimination reactions were proposed.

Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943
Keywords:
IR; Me2Sn(O2PCl2)2; Me3SnO2PCl2; Ph3SnO2PCl2; TG-DTA

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