Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 44: Issue 2
Electronegativity force of cations and thermal decomposition of complex fluorides
I. Thermal decomposition of fluorosilicates
Authors:
J. Zachara Warsaw University of Technology Department of Chemistry Noakowskiego 3 00-664 Warsaw Poland Noakowskiego 3 00-664 Warsaw Poland

Search for other papers by J. Zachara in
Current site
Google Scholar
PubMed Close
and
W. Wiśniewski Warsaw University of Technology Department of Chemistry Noakowskiego 3 00-664 Warsaw Poland Noakowskiego 3 00-664 Warsaw Poland

Search for other papers by W. Wiśniewski in
Current site
Google Scholar
PubMed Close
Pages:
363–373
Online Publication Date:
06 Jul 2007
Publication Date:
01 Feb 1995
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02636127
Keywords:
complex fluorides; electronegativity force; IR; thermal decomposition; X-ray
Restricted access

Abstract  

The thermal decompositions of anhydrous fluorosilicates M2SiF6 (M=Li, Na, K, Rb, Cs) and MSiF6 (M=Ca, Sr, Ba) were investigated. The decompositions proceeded according to a simple acid-base mechanism with evolution of SiF4. The influence of the cationic counter-ion acidity (expressed by means of the electronegativity force) on the course of thermal decomposition was estimated quantitatively.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Mar 2024 1 2 3
Apr 2024 3 0 0
May 2024 11 0 0
Jun 2024 12 0 0
Jul 2024 2 1 1
Aug 2024 13 0 0
Sep 2024 5 0 0