Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 44: Issue 4
Electronegativity force of cations and thermal decomposition of complex fluorides
II. Thermal decomposition of fluoroborates
Authors:
J. Zachara Warsaw University of Technology Department of Chemistry Noakowskiego 3 00-664 Warsaw Poland

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W. Wišniewski Warsaw University of Technology Department of Chemistry Noakowskiego 3 00-664 Warsaw Poland

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Pages:
929–935
Online Publication Date:
09 Jan 2007
Publication Date:
01 Apr 1995
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02547276
Keywords:
complexes; electronegativity; fluoroborates
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Abstract  

The thermal decomposition of anhydrous fluoroborates MBF4 (M=Li, Na, K, Rb, Cs) and M(BF4)2 (M=Ca, Sr, Ba) was investigated. The decomposition proceeds according to a simple acid-base mechanism with evolution of BF3. The influence of the acidity of cationic counterions, expressed by the electronegativity force on the course of thermal decomposition was estimated quantitatively.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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