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  • 1 Université des Sciences et de la Technologie Houari Boumédiène Laboratoire de Thermodynamique des Solutions Dar El Beida BP 139 Alger Algérie
  • | 2 Université de Lyon I. Laboratoire de Chimie Analytique 43 Bd du 11 Novembre 1918 69622 Villeurbanne Lyon France
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Abstract  

The authors have measured the vapour pressure of the binary four systems, piperidin +1,4-dioxan, piperidin+tetrahydropyran, piperidin+tert-butyl methyl ether and N-methyl piperidin+tert-butyl methyl ether. The measurements were carried out using an isoteniscope built by J. Jose [1]. The vapour pressure, excess Gibbs free energies at 298.15 K, 303.15 K, 313.15 K, 323.15 K, 333.15 K and 343.15 K, are reported for these mixtures. The excess Gibbs free energies have been fitted to the Redlich-Kister equation.

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