Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 45: Issue 1-2
Calorimetry of electrode reaction under linear sweep-current polarization
Authors:
Hengzhong ZhangCentral South University of Technology Department of Chemistry Changsha 410083 Hunan P. R. China

Search for other papers by Hengzhong Zhang in
Current site
Google Scholar
PubMedClose
,
Pinming ZhangCentral South University of Technology Department of Chemistry Changsha 410083 Hunan P. R. China

Search for other papers by Pinming Zhang in
Current site
Google Scholar
PubMedClose
, and
Zheng FangCentral South University of Technology Department of Chemistry Changsha 410083 Hunan P. R. China

Search for other papers by Zheng Fang in
Current site
Google Scholar
PubMedClose
View More View Less
Pages:
151–156
Online Publication Date:
18 Jan 2007
Publication Date:
01 Jul 1995
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02548674
Keywords:
electrode reaction; enthalpy change; sweep-current; thermoelectrochemistry
Restricted access

Abstract  

The mathematical-physical equation concerning the process of calorimetry of electrode reactions was deduced, and the corresponding solutions were obtained respectively for the period of the electrochemical polarization and that of the natural cooling. The calorimetry of the anodic oxidation of ferrocyanide to ferricyanide under linear sweep-current polarization was carried out, the obtained apparent enthalpy change of the electrode reaction agreed well with that obtained by the calorimetry with constant currents. The developed calorimetry with linear sweep-current and the data processing method are applicable for quick determination of apparent enthalpy changes of electrode reactions.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Oct 2022 1 0 0
Nov 2022 0 0 0
Dec 2022 1 0 0
Jan 2023 0 0 0
Feb 2023 0 0 0
Mar 2023 1 0 0
Apr 2023 0 0 0