Authors:
Zihui Meng Xian Modern Chemistry Research Institute 710061 Xian Shaanxi P. R. China

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Rongzu Hu Xian Modern Chemistry Research Institute 710061 Xian Shaanxi P. R. China

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Abstract  

From measurements of the enthalpy of solution of metal salts of 3-nitro-1,2,4-triazol-5-one (NTO) in water, the standard enthalpies of formation of KNTO·H2O, Ba(NTO)2·3H2O, LiNTO·2H2O, Ca(NTO)2·4H2O and Gd(NTO)3·7H2O were determined as −(676.9±2.6), −(1627.0±2.5), −(966.6.3±2.2), −(1905.5±4.4) and −(3020.1±6.4) kJ·mol−1, respectively. From measurements of the enthalpy of precipitation of KNTO·H2O crystal with Pb(NO3)2(aq), CuSO4(aq) and Zn(NO3)2(aq), the standard enthalpies of formation of Pb(NTO)2·H2O, Cu(NTO)2·2H2O and Zn(NTO)2·H2O were determined as −(247.4±5.9), −(712.1±5.4) and −(628.8±5.7) kJ·mol−1, respectively.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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