Abstract
The pseudobinary systems ACl−FeCl3 (A=Na, K, Rb, Cs) were reinvestigated by means of differential thermal analysis and X-ray powder diffraction. The existence of the compounds AFeCl4 (A=Na−Cs) and Cs3Fe2Cl9 could be confirmed; Cs3Fe2Cl9 is a stable compound which decomposes to CsCl and CsFeCl4 above 270°C. Additionally, two Rb-compounds—Rb3FeCl6 and Rb3Fe2Cl9—were found, which decompose, when heated, in the solid state. Rb3Fe2Cl9 is isotypic with the analogous Cs-compound; Rb3FeCl6 has the Cs3BiCl6 structure. Cs3FeCl6 is isotypic with Cs3CrCl6, a recently found orthorhombic variant of the elpasolite type.
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| Journal of Thermal Analysis and Calorimetry | |
|---|---|
| Language | English |
| Size | A4 |
| Year of Foundation |
1969 |
| Volumes per Year |
1 |
| Issues per Year |
24 |
| Founder | Akadémiai Kiadó |
| Founder's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. |
| Publisher | Akadémiai Kiadó Springer Nature Switzerland AG |
| Publisher's Address |
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11. |
| Responsible Publisher |
Chief Executive Officer, Akadémiai Kiadó |
| ISSN | 1388-6150 (Print) |
| ISSN | 1588-2926 (Online) |
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Temperature dependence of the rate of reaction in thermal analysis
The Arrhenius equation in condensed phase kinetics
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AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
Copyright Akadémiai Kiadó AKJournals is the trademark of Akadémiai Kiadó's journal publishing business branch.
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