Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 45: Issue 3
Thermal and structural studies of the chloro complexes of cobalt, nickel and copper with 3-phenylpyridine
Authors:
B. CarsonNapier University Department of Applied Chemical and Physical Sciences EH10 5DT Edinburgh Scotland

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G. KenesseyTechnical University of Budapest Thermoanalytical Research Group, Department of Inorganic Chemistry H-1521 Hungary

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J. AllanNapier University Department of Applied Chemical and Physical Sciences EH10 5DT Edinburgh Scotland

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G. LiptayTechnical University of Budapest Thermoanalytical Research Group, Department of Inorganic Chemistry H-1521 Hungary

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Pages:
369–374
Online Publication Date:
09 Jan 2007
Publication Date:
01 Sep 1995
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf02548770
Keywords:
chloro complexes; structural studies
Restricted access

Abstract  

The chloro complexes of cobalt, nickel and copper with 3-phenylpyridine were prepared in ethanolic solution from which solid compounds were isolated. The cobalt and copper complexes have stoichiometry M2LCl4 while the nickel complex has stoichiometry NiLCl2. The suggested structure for the cobalt and copper complexes is tetrahedral, while for the nickel complex it is octahedral. Thermal analysis studies show that the cobalt and copper complexes form intermediate complexes before their metal oxides are produced. The nickel complex also forms an intermediate complex and then nickel chloride before the nickel oxide is obtained.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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