The stability of Supersulphated Cement (SSC) is investigated at 95°C when subjected to relative humidities of 100, 53 and
11% of water vapour. Previously  investigations at 25, 50, 75°C under the same conditions of humidity reported the stability
of ettringite, one of the initial hydration products. At 95°C, decomposition of ettringite, is found at all humidities and
is rapid at 100% relative humidity. The hydration products of cement pastes at a water cement ratio of 0.27 were determined
by thermogravimetry (TG) and X-ray diffraction (XRD).
The formation of the hydragarnet, plazolite is recorded during the decomposition/dehydration process enhanced by possible
carbonation. Rehydration studies on the products after storage for up to 9 months were carried out using distilled water and
the samples tested for ettringite content. It is concluded that ettringite in SSC is inherently unstable at 95°C.