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  • 1 Wroclaw University of Medicine Department of Inorganic Chemistry ul. Szewska 38 50 139 Wrocław Poland
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Abstract  

The phase diagram for the CuBr−TlBr system was investigated using the differential thermal analysis completed by the X-ray powder diffraction data. Three intermediate phases were found: Tl2CuBr3 (stable from room temperature up to 234°C where decomposes in the solid state), Tl3Cu2Br5 (stable between 168°C and its incongruent melting point 262°C) and a nonstochiometric δ phase (centered about 75 mol% CuBr and stable above about 240°C).

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