Indispensability of the use of calorimetric measurements for the description of adsorption processes in microporous systems

G. Rychlicki; A. Terzyk

doi:10.1007/bf02547464

Journal of Thermal Analysis and Calorimetry

Volume/Issue:: Volume 45: Issue 5

Indispensability of the use of calorimetric measurements for the description of adsorption processes in microporous systems

Authors: G. Rychlicki¹ and A. Terzyk¹

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¹ N. Copernicus University Faculty of Chemistry Gagarina 7 87-100 Toruń Poland

DOI:: https://doi.org/10.1007/bf02547464

Page Count:: 961–965

Publication Date:: 01 Nov 1995

Online Publication Date:: 09 Jan 2007

Article Category:: Research Article

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Abstract

The role of calorimetry in adsorption is shortly reviewed. The differences between calorimetric adsorption heats and those calculated from Clausius-Clapeyron equation for the systems ethanol-activated carbons are presented. Obtained results, together with the results presented previously for other adsorbates, confirm that calorimetry is indispensable for a real thermodynamical description of the adsorption process in this type of system.