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  • 1 Department of Chemistry RUCA Groenenborgerlaan 171 B-2020 Antwerp Belgium
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Oxathioamidates (CSNR1R2COOKR1=R2=H (A),R1=H andR2=CH3 (B),R1,=R2=CH3 (C)) can act as O, S donors and form pentaatomic ring systems with divalent metals (M(II)=Mn, Fe, Co, Ni, Cu, Zn). Vibrational spectra and thermal analysis provide information on the amount and nature of associated water molecules. The dehydration of MA2(H2O)2 (M=Mn, Fe, Co, Ni) can be very well explained by the C.F.S.E. (crystal field stabilization energy) for weak field octahedral complexes. The complexes with ligand A and B decompose to form polymers by deprotonation on the thioamide group. The proposed structures are confirmed by the vibrational spectra. For ligand C no stable intermediates are formed during heating, degradation proceeds until metal sulphide remains.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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