Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 47: Issue 1
Enthalpies of dilution for 1∶3 and 3∶1 electrolytes aqueous solutions
Authors:
J. M. Arsuaga Departamento de Química-Física I, Facultad de Quimica Universidad Complutense 28040 Madrid

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,
F. Fernández-Martín Instituto del Frío C.S.I.C. 28040 Madrid Spain

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, and
J. Núñez Departamento de Química-Física I, Facultad de Quimica Universidad Complutense 28040 Madrid

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Pages:
291–297
Online Publication Date:
03 Aug 2005
Publication Date:
01 Jul 1996
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01982708
Keywords:
aqueous electrolyte; enthalpy of dilution; isoperobolic calorimetry
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The enthalpies of dilution for aqueous solutions of [Co(cn)3)]Cl3, [Co(pn)3)]Cl3 and [Co(tn)3]Cl3, (whereen=1,2-diaminoethane,pn=1,2-diaminopropane, andtn=1,3-diaminopropane) have been measured at 298.15 K, and up to 1 mol kg−1+, using a new large isoperibol calorimeter by the “long-jump” method. Relative apparent molar enthalpies,291-01, have been extracted as an empirical equation relatingLΦ andm. We have compared our complex salts with the 3∶1 and 1∶3 aqueous systems found in the literature. Theoretical predictions for 1∶3 and 3∶1 electrolytes in the Restricted Primitive Model are also shown.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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