Authors:
Zhou Bao-xue Department of Chemistry Shandong Normal University 250014 Jinan

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Zhong Wei-ke Shandong Provincial Environmental Monitoring Center 250014 Jinan

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Zou Li-zhuang Department of Chemistry Shandong Yantai Teacher's College 264025 Yantai P. R. China

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Wang Xiao-ling Department of Chemistry Shandong Yantai Teacher's College 264025 Yantai P. R. China

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Barium(II) tetraphenylborate, Ba(Bph4))2·4H2O was prepared, and its decomposition mechanism was studied by means of TG and DTA. The products of thermal decomposition were examined by means of gas chromatography and chemical methods. A kinetic analysis of the first stage of thermal decomposition was made on the basis of TG and DTG curves and kinetic parameters were obtained from an analysis of the TG and DTG curves using integral and differential methods. The most probable kinetic function was suggested by comparison of kinetic parameters. A mathematical expression was derived for the kinetic compensation effect.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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