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L. Katsikas Faculty of Technology and Metallurgy Belgrade University Karnegijeva 4 P.O.B. 494 YU-11001 Belgrade Serbia Yugoslavia

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T. A. Djakov Faculty of Technology and Metallurgy Belgrade University Karnegijeva 4 P.O.B. 494 YU-11001 Belgrade Serbia Yugoslavia

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J. M. Filipović Faculty of Technology and Metallurgy Belgrade University Karnegijeva 4 P.O.B. 494 YU-11001 Belgrade Serbia Yugoslavia

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J. S. Veličković Faculty of Technology and Metallurgy Belgrade University Karnegijeva 4 P.O.B. 494 YU-11001 Belgrade Serbia Yugoslavia

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I. G. Popovic Faculty of Technology and Metallurgy Belgrade University Karnegijeva 4 P.O.B. 494 YU-11001 Belgrade Serbia Yugoslavia

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The oxidative and non-oxidative degradation of poly(di-methoxy-), poly(di-ethoxy-), poly(di-iso-propoxy-) and poly(di-n-butoxyethyl itaconate) were investigated by thermogravimetry. Characteristic degradation temperatures and apparent activation energies of degradation were determined for the non-oxidative degradation of all the investigated polymers. It was not possible to determine these characteristics in the presence of oxygen as the degradation was accompanied by a secondary exothermic reaction. Based on examination of the monomers, it is supposed that the exothermic reaction is a repolymerisation of the monomers released during the earlier stages of polymer degradation.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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