Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 48: Issue 2
Determination of the reaction heat and studies of thermodynamic functions
Hydrolytic polymerization of chromium(III) at relatively high concentrations by microcalorimetry
Authors:
Lu Chengxue Department of Chemistry Shandong University 250100 Jinan P. R. China

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,
Yu Xiufang Department of Chemistry Qufu Normal University 273165 Qufu P. R. China

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, and
Zhang Honglin Department of Chemistry Qufu Normal University 273165 Qufu P. R. China

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Pages:
327–329
Online Publication Date:
02 Aug 2005
Publication Date:
01 Feb 1997
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01979276
Keywords:
chromium(III); hydrolytic polymerization; reaction heat; thermodynamic functions
Restricted access

The hydrolytic polymerization of Cr3+ at relatively high concentrations was studied by microcalorimetry. The thermal curves were determined with a 2277 thermal activity monitor. From the curves, the identified reaction heats (δrHmσ), hydrolysis constants (K) and thermodynamic functions (δrSmσ,δrHmσ) were calculated at different temperatures.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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