Authors:
I. Popović Faculty of Technology and Metallurgy, Belgrade University, Karnegijeva 4, P.O.B. 494, 11001 Belgrade, Yugoslavia

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M. Tarabić Faculty of Technology and Metallurgy, Belgrade University, Karnegijeva 4, P.O.B. 494, 11001 Belgrade, Yugoslavia

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B. šobić Faculty of Technology and Metallurgy, Belgrade University, Karnegijeva 4, P.O.B. 494, 11001 Belgrade, Yugoslavia

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L. Katsikas Faculty of Technology and Metallurgy, Belgrade University, Karnegijeva 4, P.O.B. 494, 11001 Belgrade, Yugoslavia

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Abstract  

Polymethacrylonitrile (PMAN) was prepared by bulk, solution and precipitation polymerization. The thermal stability of the polymer, which is affected by the structure of the chain end groups, was studied by non-isothermal thermogravimetry (TG). On the basis of the differential TG curves of samples prepared by polymerization in the presence of chlorinated solvents, it may be concluded that, in addition to end-chain and random main chain scission initiated depolymerization, hydrogen chloride evolution also occurs during the thermal degradation of PMAN.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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