Authors:
D. Audette Olin Research Center, 06410-0586 Cheshire, CT USA

Search for other papers by D. Audette in
Current site
Google Scholar
PubMed
Close
,
D. Giordano Olin Research Center, 06410-0586 Cheshire, CT USA

Search for other papers by D. Giordano in
Current site
Google Scholar
PubMed
Close
, and
R. Wedlich Olin Research Center, 06410-0586 Cheshire, CT USA

Search for other papers by R. Wedlich in
Current site
Google Scholar
PubMed
Close
Restricted access

Abstract  

A method for estimating the vapor-liquid equilibria of binary liquid solutions using an Accelerating Rate Calorimeter (ARC) is described. ARC provided data in the ranges: (0–14) kPa and (300–450) K. The experimental PTx data were reduced to partial pressures and vapor phase compositions using Barker's method. The well-known system, benzene/cyclopentane, was selected to evaluate the ARC method. GC-headspace analysis confirmed the vapor phase compositions. Both GC and ARC data on the vapor phase agree with literature data to within ±0.0085 mol fraction units. Experimental pressure data agree with literature data to within ±2 kPa. Model pressure data agree with literature data to within ±1.5 kPa. Also described is the high-pressure VLE of the phosgene-chlorobenzene binary at 448 K.

  • Collapse
  • Expand

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Aug 2024 8 0 0
Sep 2024 9 0 0
Oct 2024 11 0 0
Nov 2024 2 0 0
Dec 2024 2 0 0
Jan 2025 2 0 0
Feb 2025 7 0 0