Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 49: Issue 2
Thermochemical parameters of complexes of di-isobutyldithiocarbamate with phosphorus-group elements
Authors:
A. de Souza Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, Joo Pessoa, 58059-900 Paraíba

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Fe. Neto Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, Joo Pessoa, 58059-900 Paraíba

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J. de Souza Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, Joo Pessoa, 58059-900 Paraíba

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R. Macedo Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, Joo Pessoa, 58059-900 Paraíba

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J. de Oliveira Departamento de Química, Centro de Ciências Exatas e da Natureza, Universidade Federal da Paraíba, Joo Pessoa, 58059-900 Paraíba

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C. Pinheiro Departamento de Ciências Exatas e da Natureza, Centra de Formaçâo de Professores, Universidade Federal da Paraíba, Cajazeiras, 58900-000 Paraíba, Brazil

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Pages:
679–684
Online Publication Date:
05 Aug 2005
Publication Date:
01 Aug 1997
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01996751
Keywords:
bismuth; calorimetry; dithiocarbamate; enthalpy; phosphorous
Restricted access

Abstract  

The standard molar enthalpy of formation of crystalline di-isobutyldithiocarbamate complexes of P, As, Sb and Bi(III) has been derived by solution calorimetry at 298.15 K. The corresponding standard molar enthalpies of sublimation were estimated by means of differential scanning calorimetry. From the standard molar enthalpies of formation of the gaseous chelates the homolytic and heterolytic mean metal-sulphur bond-dissociation enthalpies were calculated.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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