Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 49: Issue 3
Applications of thermal analysis in some solid-state reactions
Author: P. S. Bassi 1
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  • 1 Chemistry Department, Guru Nanak Dev University, 143006 Amritsar, India
DOI:
https://doi.org/10.1007/bf01983670
Page Count:
1153–1160
Publication Date:
01 Aug 1997
Online Publication Date:
01 Aug 1997
Article Category:
Research Article
Restricted access

Abstract

TG-DTG-DTA has been used to characterize various isomers of CoCl2·2(CH3C6H4NH2). Thermal analysis is further used to analyse the binary mixtures of these isomers. DTA recorded after different elapsed times follows the progress of reaction between cobalt chloride and benzocaine where progressively small endotherms are associated with starting materials. The application of thermal analysis to following the solid-solid reactions between metal acetates and 8-hydroxyquinoline was highlighted. The stoichiometry of such reactions was confirmed from the decrease in intensity of an endotherm as one increases the stoichiometry.

  • 1 Kambe, H. Garn, D. D. 1974 Thermal Analysis John Wiley and Sons New York.

  • 2 Brown, W. E. Dollimore, D. Galwey, A. K. 1980 Comprehensive Chemical Kinetics, Vol. 22 Elsevier Amsterdam.

  • 3 Bassi, P. S. Randhawa, B. S. Jamwal, H. S. 1983 Thermochem. Acta 71 15–15. .

  • 4 Bassi, P. S. Randhawa, B. S. Jamwal, H. S. 1985 Thermochim. Acta 86 141–141. .

  • 5 Bassi, P. S. Randhawa, B. S. Khajuria, C. M. Kaur, Sandeep 1987 J. Thermal Anal. 32 569–569. .

  • 6 Bassi, P. S. Chopra, G. S. Kaur, K. 1989 J. Thermal Anal. 35 1213–1213. .

  • 7 Bassi, P. S. Chopra, G. S. Kaur, K. 1990 Indian J. Chem. 29A 454–454.

  • 8 Bassi, P. S. Randhawa, B. S. Kaur, Sandeep 1992 Indian J. Chem. 31A 596–596.

  • 9 Bassi, P. S. Chopra, G. S. Singh, Rajinder 1996 Indian J. Chem. 35A 458–458.

  • 10 Vogel's Textbook of Practical Organic Chemistry, 5th Edition, Longman 1989, p. 701.
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943
Keywords:
solid-state reactions; thermal analysis

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