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  • 1 Chemistry Department, Birkbeck College, University of London, Gordon House, 29 Gordon Square, London WC1H OPP, UK
  • | 2 FOM Institute for Atomic and Molecular Physics, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands
  • | 3 IROE Istituto di Ricerca sulle Onde Elettromagnetiche del Consiglio Nazionale delle Ricerche, Via Panciatichi 64, 50127 Firenze, Italy
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Abstract

The basic concept of this project is to identify and then use the changes which occur in the chemical and physical properties of traditional paint media both to indicate and integrate the effects of environmental conditions on paintings. To achieve this aim, test paint films are being prepared in accordance with traditional artists' recipes. Changes in material properties are monitored using a combination of non-invasive spectroscopy (Bacci), microsensors, thermoanalytical techniques (Odlyha), and microscale analytical mass spectrometry for molecular structure analysis (Boon). The test strips are calibrated by exposure to controlled environments (light, temperature, relative humidity and noxious gases) and alterations in their properties are quantified. This provides information on the nature and rate of change at the molecular level and a data base for evaluating the molecular monitoring strips after their exposure in the field. Field sites have been selected and include various locations in the Tate Gallery (UK), Sandham Chapel (Burghclere, UK), the Uffizi Gallery (It) and the Rijksmuseum (NL). Environmental conditions of some of these locations are being evaluated at present using the glass sensors described in project EV5VCT92 0144. Small piezoelectric quartz crystal humidity sensors will be installed to determine localised variations in relative humidity and temperature on [1] Stanley Spencer paintings in Sandham Chapel and [2] Giotto's “Madonna di Ognissanti” in the Uffizi Gallery. In addition novel coatings using picture varnishes are being applied to similar piezoelectric quartz crystal sensors to evaluate the effects of environmental impact on the chemistry of varnishes on paintings. Data are also being collected on the nature of chemical and physical changes in varnishes and paint media in actual paintings at the molecular level.

  • 1 Thompson, G., “Museum Environment” Butterworth-Heinemann Series in Conservation and Museology, Oxford, UK 1994.

  • 2 Villers, C. and Hedley, G., “Evaluating Colour Change: intention, interpretation and lighting” in Measured Opinions: Collected papers on the Conservation of Paintings G. Hedley Ed. by Villers, C., United Kingdom Institute for Conservation 1993, p. 145.

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  • 3 The Uffizi Project — C. N. R, Ed., Cappellini, V., Dipartimento di Ingegneria Eiettronica Università di Firenze, Italy 1993.

  • 4 Massa, V. and Scicolone, G., Le Vernici per il Restauro Nardini Ed., Florence 1991.

  • 5 Havermans, J. B. G. A., “Effects of air pollutants on the accelerated ageing of cellulose-based materials”, International Congress on Environment /Climate ICEC-96, Rome 1996.

    • Search Google Scholar
    • Export Citation
  • 6 Leissner, J., Martin, G., Blades, N. and Redol, P., “Assessment and Monitoring the Environment of Cultural Property”, Preprints European Commission Research Workshop, “Effects of the Environment on Indoor Cultural Property”, Würzburg 1995, p. 11.

    • Search Google Scholar
    • Export Citation
  • 7 Saunders, D. Kirby, J. 1994 National Gallery Techn. Bull. 15 7979.

  • 8 Feller, R. L. 1982 Studies on the darkening of vermilion by light, Report and Studies in the History of Art National Gallery of Art Washington 180180.

    • Search Google Scholar
    • Export Citation
  • 9 Johnston-Feller, R. and Bailie, C. W., An Analysis of the optics of paint glazes: fading, Science and Technology in the Service of Conservation, Preprints of the IIC Congress, Washington 1982, p. 180.

    • Search Google Scholar
    • Export Citation
  • 10 Bacci, M., Picollo, M., Porcinai, S. and Radicati, B., “Non-Destructive Evaluation of the Colour Change of Paintings Induced by the Environment” in International Congress on Environment /Climate ICEC-96, Rome 1996.

    • Search Google Scholar
    • Export Citation
  • 11 Hedley, G., Villers, C., Bruce-Gardner, R. and MacBeth, R., “A new Method for Treating Water Damage Flaking”, Proc. ICOM Committee for Conservation, Dresden 1990.

    • Search Google Scholar
    • Export Citation
  • 12 Work performed in the context of SCICULT (Scientific Analysis for Conservation of Cultural Materials) Human Capital and Mobility Programme (ERBCHGCT920135).

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  • 13 Saunders, D. and Kirby, J., “Wavelength-Dependent Fading of Artists' Pigments” in Preprints of “Preventive Conservation Practice, Theory and Research” Ottawa, Congress 1994, p. 190.

    • Search Google Scholar
    • Export Citation
  • 14 Saunders, D. Kirby, J. 1996 Light-induced Damage: Investigating the Reciprocity Principle Preprints 11th Triennial Meeting ICOM Committee for Conservation 1 704704.

    • Search Google Scholar
    • Export Citation
  • 15 Quye, A. Wouters, J. Boon, J. J. 1996 A Preliminary Study of Light-ageing Effects on the Analysis of Naturaal Flavanoid-dyed Wools by Photodiode Array HPLC and Direct Temperature Mass Spectrometry Preprints 11th Triennial Meeting ICOM Committee for Conservation 1 704704.

    • Search Google Scholar
    • Export Citation
  • 16 Staniforth, S., Hayes, B. and Bullock, L., “Appropriate Technologies for Relative Humidity Control for Museum Collections housed in Historic Buildings” in Preventive Conservation Practice, Theory and Research, Preprints of the Contributions to the Ottawa Congress 1994, p. 123.

    • Search Google Scholar
    • Export Citation
  • 17 Van der Doelen, G. A. and Boon, J. J., “Mass Spectrometry of Resinous Compounds from Paintings: Characterisation of Dammar and Naturally Aged Dammar Varnish by DTMS and HPLC/GCMS” in Preprints SSCR Resins Ancient and Modern, Aberdeen 1995, p. 70.

    • Search Google Scholar
    • Export Citation
  • 18 Odlyha, M. 1991 J. Thermal Anal. 37 14311431. .

  • 19 Rasti, F. Scott, G. 1980 Studies in Conservation 25 145145. .

  • 20 Chan, A., Felder-Casagrande, S., Foster, G. and Odlyha, M., “Development of Environmentally Benign Coatings based on Artists' Materials” in Preprints 11th Congress on Thermal Analysis and Calorimetry, Philadelphia 1996, p. 359.

    • Search Google Scholar
    • Export Citation
  • 21 Felder-Casagrande, S. Odlyha, M. 1997 J. Thermal Anal. 49 15851585. .

  • 22 Foster, G. and Odlyha, M., J. Thermal Anal., in press.

  • 23 Odlyha, M. and Foster, G., “Glass Transition Temperature Measurements of Artists' Materials” in Preprints of International Seminar on Materials and Thermal Properties in Cultural Heritage, Rome 1996 p. 16.

    • Search Google Scholar
    • Export Citation
  • 24 Slater, J. M., private communication.

  • 25 Burnstock, A., Calwell, M. and Odlyha, M., “A Technical Examination of Surface Deterioration of Stanley Spencer's Paintings at Sandham Memorial Chapel” in Proc. ICOM Committee, Washington 1993, p. 231.

    • Search Google Scholar
    • Export Citation
  • 26 Odlyha, M., “The role of Thermoanalytical Techniques in the Characterisation of Samples from Turner's “The Opening of the Walhalla, 1842”” in Turner's Painting Techniques in Context, Ed. Townsend, J. H. London UKIC 1995, p. 29.

    • Search Google Scholar
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  • 27 Boon, J. J., Pureveen, J., Rainford, D. and Townsend, J. H., “The Opening of the Walhalla, 1842: Studies on the Molecular Signature of Turner's Paint by Direct Temperature Resolved Mass Spectrometry (DTMS)” in Turner's Painting Techniques in Context, Ed. Townsend, J. H. London UKIC 1995, p. 21.

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  • 28 Bacci, M. Baronti, S. Casini, A. Lotti, F. Piccollo, M. Casazza, O. 1992 Mat. Res. Sym. Proc. 267 265265.

  • 29 Boon, J. J., van der Berg, K.-J., Pureveen, J., van der Doelen, G., Groen, K., van Och, J. and van Grevenstein, A., “Direct Temperature Resolved Mass Spectrometry (DTMS) as a Tool to Study Painted Art: A Case Study of the Eendenfamilie” by W. Maris, a 19th Century Dutch Impressionist Painter, Proc. 43rd ASMS Conference on Mass Spectrometry and Allied Topics, Atlanta 1995, p. 745.

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  • 30 Piccollo, M., Bacci, M., Lotti, F., Linari, R., Radicati, B. and Stefani, L., “Non-destructive identification of pigments in the Dome of S. Maria del Fiore (Florence)”, in Preprints of the 1st International Congress on Science and Technology for the Safeguard of Cultural Heritage in the Mediterranean Basin, Catania 1995, p. 231.

    • Search Google Scholar
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  • 31 Foster, G. and Odlyha, M., Internal Report to the National Trust (UK) 1996.

  • 32 Foster, G., “Simultaneous non-invasive microwave dielectric spectroscopy and dynamic mechanical analysis for studying drying processes in complex heterogeneous materials” in Preprints 11th congress on thermal analysis and Calorimetry, Philadelphia 1996, p. 286.

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    • Export Citation
  • 33 Odlyha, M., Foster, G. and Scharff, M., “Non-Invasive Evaluation of Moisture Sorption and Desorption Processes in Canvases” in Preprint.

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  • Impact Factor (2019): 2.731
  • Scimago Journal Rank (2019): 0.415
  • SJR Hirsch-Index (2019): 87
  • SJR Quartile Score (2019): Q3 Condensed Matter Physics
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • Impact Factor (2018): 2.471
  • Scimago Journal Rank (2018): 0.634
  • SJR Hirsch-Index (2018): 78
  • SJR Quartile Score (2018): Q2 Condensed Matter Physics
  • SJR Quartile Score (2018): Q2 Physical and Theoretical Chemistry

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
4
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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