Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 50: Issue 1-2

A mathematical model for Modulated Differential Scanning Calorimetry

Authors:
,
A. Lacey Department of Mathematics, Heriot-Watt University, EH14 4AS Riccarton, Edinburgh

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C. Nikolopoulos Department of Mathematics, Heriot-Watt University, EH14 4AS Riccarton, Edinburgh

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M. Reading ICI Paints, Wexham Road, SL2 5DS Slough, Berks UK

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Pages:
279–333
Online Publication Date:
02 Aug 2005
Publication Date:
01 Sep 1997
Article Category:
Research Article
DOI:
https://doi.org/10.1007/bf01979568
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Abstract  

Reading and co-workers introduced a new technique a few years ago called Modulated Differential Scanning Calorimetry or MDSC. Here the first part of a theoretical analysis for this technique is given. A simple mathematical model for modulated differential scanning calorimetry in the form of an ordinary differential equation is derived. The model is analysed to find the effect of a kinetic event in the form of a chemical reaction. Some possible sources of error are discussed. A more sophisticated version of the model allowing for spatial variation in a calorimeter is developed and it is seen how it can be reduced to the earlier model. Some preliminary work on a phase change is also presented.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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