Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 53: Issue 2
Kinetics and Mechanism of the Thermal Decomposition of M(NO3)2·nH2O (M=Cu, Co, Ni)
Authors:
Ž. Živković University of Belgrade Technical Faculty 19210 Bor Yugoslavia 19210 Bor Yugoslavia

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D. Živković University of Belgrade Technical Faculty 19210 Bor Yugoslavia 19210 Bor Yugoslavia

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D. Grujičić University of Belgrade Technical Faculty 19210 Bor Yugoslavia 19210 Bor Yugoslavia

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Pages:
617–623
Online Publication Date:
02 Nov 2004
Publication Date:
01 Jul 1998
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010170231923
Keywords:
kinetics; nitrates; thermal decomposition
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Abstract  

This paper presents the results of simultaneous DTA-TG-DTG and DSC studies on the thermal decomposition of Cu(NO3)23H2O, Co(NO3)26H2O and Ni(NO3)26H2O in an air atmosphere. The mechanism and enthalpies of the investigated processes were determined, as well as the kinetic parameters of the processes run under non-isothermal conditions by means of Kissinger's method. The dependence of the activation energy on the ionic radius of the cations building up the crystal lattices of the investigated compounds was also studied.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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