Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 56: Issue 1
Calorimetric Study of the Acidity of a New Family of Mesoporous Catalysts
Authors:
S. d'Arbonneau Institut de Recherches sur la Catalyse, CNRS 2 avenue Einstein 69626 Villeurbanne Cedex France 2 avenue Einstein 69626 Villeurbanne Cedex France

Search for other papers by S. d'Arbonneau in
Current site
Google Scholar
PubMed Close
,
A. Tuel Institut de Recherches sur la Catalyse, CNRS 2 avenue Einstein 69626 Villeurbanne Cedex France 2 avenue Einstein 69626 Villeurbanne Cedex France

Search for other papers by A. Tuel in
Current site
Google Scholar
PubMed Close
, and
A. Auroux Institut de Recherches sur la Catalyse, CNRS 2 avenue Einstein 69626 Villeurbanne Cedex France 2 avenue Einstein 69626 Villeurbanne Cedex France

Search for other papers by A. Auroux in
Current site
Google Scholar
PubMed Close
Pages:
287–296
Online Publication Date:
03 Nov 2004
Publication Date:
01 Jul 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010126012231
Keywords:
acidity; AlPO; calorimetry; mesoporous catalysts; SAPO
Restricted access

Abstract  

Thermally stable mesoporous aluminophosphates (AIPO) and silicoaluminophosphates (SAPO) were prepared at room temperature in the presence of a cationic surfactant and an organic base. These materials possess high surface areas and regular mesopores of approximately 35 Å diameter. By contrast to microporous crystalline aluminophosphate molecular sieves, mesoporous compounds are amorphous and characterized by Al/P ratios greater than 1. These particularities are responsible for a strong Lewis acidity, as evidenced by ammonia adsorption microcalorimetry. Mesoporous materials are more acidic than the microporous analogues and the amount of strong acid sites increases with the silicon content.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 9 0 0
May 2024 1 0 0
Jun 2024 13 0 0
Jul 2024 34 0 0
Aug 2024 12 0 0
Sep 2024 8 0 0
Oct 2024 4 0 0