Low Temperature Specific Heat Capacity of 3d Transition Metal Chlorine Boracites (T3B7O13Cl; T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg)

W. Schnelle; E. Gmelin; O. Crottaz; H. Schmid

doi:10.1023/a:1010158919499

Journal of Thermal Analysis and Calorimetry

Volume/Issue:: Volume 56: Issue 1

Low Temperature Specific Heat Capacity of 3d Transition Metal Chlorine Boracites (T3B7O13Cl; T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg)

Authors:

W. Schnelle

W. Schnelle Max-Planck-Institut für Festkörperforschung Heisenbergstr. 1 D-70569 Stuttgart Germany Heisenbergstr. 1 D-70569 Stuttgart Germany

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E. Gmelin

E. Gmelin Max-Planck-Institut für Festkörperforschung Heisenbergstr. 1 D-70569 Stuttgart Germany Heisenbergstr. 1 D-70569 Stuttgart Germany

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O. Crottaz

O. Crottaz Université de Genève Dept. de Chimie Minérale, Analytique et Appliquée 30 Quai Ernest-Ansermet CH-1211 Genève 4 Switzerland 30 Quai Ernest-Ansermet CH-1211 Genève 4 Switzerland

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, and

H. Schmid

H. Schmid Université de Genève Dept. de Chimie Minérale, Analytique et Appliquée 30 Quai Ernest-Ansermet CH-1211 Genève 4 Switzerland 30 Quai Ernest-Ansermet CH-1211 Genève 4 Switzerland

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Pages:: 365–370

Online Publication Date:: 03 Nov 2004

Publication Date:: 01 Jul 1999

Article Category:: Research Article

DOI:: https://doi.org/10.1023/a:1010158919499

Keywords:: magnetic phase transition; specific heat capacity; transition metal compound

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Abstract

The heat capacities of eight chlorine boracites T₃B₇O₁₃Cl (T=Cr, Mn, Fe, Co, Ni, Cu, Zn or Mg) have been measured in the temperature range 2 to 100 K. Magnetic phase transitions occur below 20 K in the compounds studied except in the two non-magnetic substances Zn₃B₇O₁₃Cl and Mg₃B₇O₁₃Cl. The magnetic specific heat capacities give information on magnetic ground state of the transition metals and the entropy related to the phase transitions.

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Journal of Thermal Analysis and Calorimetry

Print ISSN:: 1388-6150

Online ISSN:: 1572-8943

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Journal of Thermal Analysis and Calorimetry
Language	English
Size	A4
Year of Foundation	1969
Volumes per Year	1
Issues per Year	24
Founder	Akadémiai Kiadó
Founder's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	1388-6150 (Print)
ISSN	1588-2926 (Online)