Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 56: Issue 2
Thermal Behaviour of Complexes of Antipyrine Derivatives
Authors:
I. Labádi József Attila University Department of Inorganic and Analytical Chemistry H-6701 Szeged P.O. Box 440 Hungary H-6701 Szeged P.O. Box 440 Hungary

Search for other papers by I. Labádi in
Current site
Google Scholar
PubMed Close
,
R. Tudose Romanian Academy, Timişoara Branch Inorganic Chemistry Laboratory RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania

Search for other papers by R. Tudose in
Current site
Google Scholar
PubMed Close
,
I. Fejér Romanian Academy, Timişoara Branch Inorganic Chemistry Laboratory RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania

Search for other papers by I. Fejér in
Current site
Google Scholar
PubMed Close
,
Z. Jóri József Attila University Department of Inorganic and Analytical Chemistry H-6701 Szeged P.O. Box 440 Hungary H-6701 Szeged P.O. Box 440 Hungary

Search for other papers by Z. Jóri in
Current site
Google Scholar
PubMed Close
, and
O. Costisor Romanian Academy, Timişoara Branch Inorganic Chemistry Laboratory RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania RO-1900 Timişoara, 24, Bul. Mihai Viteazu Romania

Search for other papers by O. Costisor in
Current site
Google Scholar
PubMed Close
Pages:
553–559
Online Publication Date:
08 Dec 2004
Publication Date:
01 Sep 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010108812444
Keywords:
Co(II) and Cu(II) ions; mixed ligand complexes; pyrazolonic Mannich bases; thermal behaviour; 2-aminobenzothiazole
Restricted access

Abstract  

Parent and mixed ligand complexes of cobalt and copper with antipyrine derivatives of 1,2-ethanediamine or piperazine and with 2-aminobenzothiazole (TAB) were synthesized and their thermal behaviour was investigated. The complexes contain N,N′-bis(4-antipyrylmethyl)-piperazine (BAMP) or N,N′-tetra(4-antipyrylmethyl)-1,2-diaminoethane (TAMEN) or/and TAB as ligand, and Cl−, ClO4− or SCN−. The complexes decompose with the evolution of heat. The decomposition route depends on the presence of ClO4−. If the ClO4− is not coordinated, it oxidizes the TAB and BAMP or TAMEN and the decomposition is explosive.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Mar 2024 4 0 0
Apr 2024 5 0 0
May 2024 2 0 0
Jun 2024 7 0 0
Jul 2024 12 0 0
Aug 2024 30 0 0
Sep 2024 0 0 0