Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 56: Issue 2
Isothermal and Non-Isothermal Kinetics When Mechanistic Information Available
Authors:
N. Sbirrazzuoli Université de Nice-Sophia Antipolis Laboratoire de Thermodynamique Expérimentale C.N.R.S. U.M.R. 6595 06108 Nice Cedex 2 06108 Nice Cedex 2

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L. Vincent Université de Nice-Sophia Antipolis Laboratoire de Thermodynamique Expérimentale C.N.R.S. U.M.R. 6595 06108 Nice Cedex 2 06108 Nice Cedex 2

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J. Bouillard Centre de Recherche d'Ingénierie et de Technologie CRIT, Rhône-Poulenc Industrialisation 69153 Décines Charpieu Cedex France 69153 Décines Charpieu Cedex France

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L. Elégant Université de Nice-Sophia Antipolis Laboratoire de Thermodynamique Expérimentale C.N.R.S. U.M.R. 6595 06108 Nice Cedex 2 06108 Nice Cedex 2

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Pages:
783–792
Online Publication Date:
08 Dec 2004
Publication Date:
01 Sep 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010110307418
Keywords:
complex process; DSC; isoconversional methods; kinetics; model-free kinetics; peak maximum evolution methods; simulations
Restricted access

Abstract  

In the case of a complex mechanism of two parallel independent reactions, peak maximum evolution methods and model-fitting methods give only a mean value of the kinetic parameters, while isoconversional methods are useful to describe the complexity of the mechanism. Isothermal and non-isothermal isoconversional methods can be used to elucidate the kinetics of the process. Nevertheless, isothermal isoconversional methods can be limited by restrictions on the temperature regions experimentally available because of duration times or detection limits.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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