Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 56: Issue 3
The Thermal Decomposition of Triple-Base Propellants
Authors:
M. Stanković Military Technical Institute of the Yugoslav Army Katanićeva 15 11000 Belgrade Katanićeva 15 11000 Belgrade

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,
V. Kapor Military Technical Institute of the Yugoslav Army Katanićeva 15 11000 Belgrade Katanićeva 15 11000 Belgrade

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, and
S. Petrović Faculty of Technology and Metallurgy Karnegijeva 4 11000 Belgrade Yugoslavia Karnegijeva 4 11000 Belgrade Yugoslavia

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Pages:
1383–1388
Online Publication Date:
16 Aug 2006
Publication Date:
01 Nov 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010118826015
Keywords:
ASTM method; Borchardt-Daniels method; double-base propellant; Freeman-Carroll method; kinetic parameters; Kissinger method; nitroguanidine; Rogers-Morris method; triple-base propellant
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Abstract  

The thermal decompositions of a double-base propellant (DB), five triple-base propellants (TB) and nitroguanidine (NGV) were examined. The kinetic parameters were evaluated using the ASTM, Kissinger, Rogers-Morris, Freeman-Carroll and Borchardt-Daniels methods. The values of the orders of some of the chemical reactions (n), like some values of activation energies (Ea), do not have any physical meaning, but they represent the manner of propellant decomposition and prove that the mechanism of the reaction changes during the decomposition process. As a result of this fact, differences appear in the evaluated kinetic parameters between various methods.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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