Authors:
A. Saiki Tokyo Institute of Technology O-okayama Department of Inorganic Materials Maguro-ku Tokyo Japan Maguro-ku Tokyo Japan

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H. Funakubo Tokyo Institute of Technology O-okayama Department of Inorganic Materials Maguro-ku Tokyo Japan Maguro-ku Tokyo Japan

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N. Mizutani Tokyo Institute of Technology O-okayama Department of Inorganic Materials Maguro-ku Tokyo Japan Maguro-ku Tokyo Japan

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K. Shinozaki Tokyo Institute of Technology O-okayama Department of Inorganic Materials Maguro-ku Tokyo Japan Maguro-ku Tokyo Japan

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T. Bak The University of New South Wales Centre for Materials Research in Energy Conversion School of Materials Science and Engineering Sydney NSW 2052 Australia Sydney NSW 2052 Australia

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J. Nowotny The University of New South Wales Centre for Materials Research in Energy Conversion School of Materials Science and Engineering Sydney NSW 2052 Australia Sydney NSW 2052 Australia

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M. Rekas The University of New South Wales Centre for Materials Research in Energy Conversion School of Materials Science and Engineering Sydney NSW 2052 Australia Sydney NSW 2052 Australia

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C. Sorrel The University of New South Wales Centre for Materials Research in Energy Conversion School of Materials Science and Engineering Sydney NSW 2052 Australia Sydney NSW 2052 Australia

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Abstract  

The extent of the surface charge, that develops during oxidation of zirconia, is determined using work function measurements for both bulk specimen and thin films. The bulk specimen of yttria-doped zirconia (10 mol%) exhibits maxima of the surface electrical effect at 373 and 973 K (130 and 280 mV, respectively) that can be considered in terms of oxygen chemisorption and oxygen non-stoichiometry. Thin film of undoped zirconia exhibits a maximum at 473 K (260 eV). Addition of yttria (10 mol%) to the thin film results in a substantial reduction of the maximum, to about 140 eV, that is shifted up to 600 K.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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