Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 58: Issue 2
Thermal Decomposition Kinetics of the Zn(II) Complex with Norfloxacin in Static Air Atmosphere
Authors:
J. Zhang Hebei Teachers' University Experimental Center Shijiazhuang 050016 P. R. China Shijiazhuang 050016 P. R. China

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L. Ge Hebei Teachers' University Experimental Center Shijiazhuang 050016 P. R. China Shijiazhuang 050016 P. R. China

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X. Zhang Hebei University of Science and Technology Fundamental Department Shijiazhuang 050018 P. R. China Shijiazhuang 050018 P. R. China

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Y. Dai Shijiazhuang Railway College Fundamental Department Shijiazhuang 050043 P. R. China Shijiazhuang 050043 P. R. China

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H. Chen Hebei Teachers' University Department of Mathematics Shijiazhuang 050016 P. R. China Shijiazhuang 050016 P. R. China

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L. Mo Hebei Teachers' University Experimental Center Shijiazhuang 050016 P. R. China Shijiazhuang 050016 P. R. China

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Pages:
269–278
Online Publication Date:
25 Oct 2004
Publication Date:
25 Nov 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010142928608
Keywords:
non-isothermal kinetics; norfloxacin; thermal decomposition; Zn(II) complex
Restricted access

Abstract  

The thermal decomposition of Zn[NFA]25H2O (NFA=C16H18FN3O3, norfloxacin) and its kinetics were studied under non-isothermal conditions in air by TG-DTG and DTA methods. The intermediate and residue for each decomposition were identified from the TG curve. The non-isothermal kinetic data were analyzed by means of the Achar method and the Madhusudanan-Krishnan-Ninan (MKN) method. The possible reaction mechanisms were investigated by comparing the kinetic parameters. The kinetic equation for the second stage can be expressed as d/dt=Aexp(–E/RT)(1–).

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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