Authors:
N. He

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D. Li Teachers' College of Xiangtan Department of Chemistry Xiangtan 411100 P. R. China Xiangtan 411100 P. R. China

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M. Tu Nanjing University Department of Chemistry Nanjing 210093 P. R. China Nanjing 210093 P. R. China

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J. Shen Nanjing University Department of Chemistry Nanjing 210093 P. R. China Nanjing 210093 P. R. China

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S. Bao Nanjing University Department of Chemistry Nanjing 210093 P. R. China Nanjing 210093 P. R. China

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Q. Xu Nanjing University Department of Chemistry Nanjing 210093 P. R. China Nanjing 210093 P. R. China

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Abstract  

The acidity of mesoporous materials FeSiMCM-41, LaSiMCM-41, SiMCM-41, AlSiMCM-41 and HAlSiMCM-41 has been investigated by microcalorimetric studies of the adsorption of ammonia and temperature programmed ammonia desorption method. In the initial stage, the acid strength sequence is SiMCM-41>HAlSiMCM-41>AlSiMCM-41>FeSiMCM-41>LaSiMCM-41, in agreement with that found for microporous molecular sieves materials. A small number of strong acid sites of SiMCM-41 may result from the aluminum impurity contained in the silica source material. The acid density sequence is HAlSiMCM-41>AlSiMCM-41>FeSiMCM-41>LaSiMCM-41SiMCM-41 and can be explained by the studies of existing states of trivalent atoms in these samples reported in previous work. Since some NH3-TPD plots of these samples show the profiles that could not be back to baseline at elevated temperature, the technique of microcalorimetric adsorption is preferable in studying these samples.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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