Authors:
N. Hurduc Asachi Technical University, Bd Department of Macromolecules, Gh Copou 11A 6600 Iasi Romania Copou 11A 6600 Iasi Romania

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N. Dragoi A. I. Cuza University Department of Physical Chemistry Bd. Mangeron 6600 Iasi Romania Bd. Mangeron 6600 Iasi Romania

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C. Ghirvu A. I. Cuza University Department of Physical Chemistry Bd. Mangeron 6600 Iasi Romania Bd. Mangeron 6600 Iasi Romania

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N. Hurduc A. I. Cuza University Department of Physical Chemistry Bd. Mangeron 6600 Iasi Romania Bd. Mangeron 6600 Iasi Romania

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Abstract  

A study was made of the influence of the chemical structure of the chains on the thermal stability of a series of copolyethers obtained from 3,3-bis(chloromethyl)oxetane and various bisphenols: 4,4'-dihydroxyazobenzene, 4,4'-dihydroxydiphenyl, 4,4'-thiodiphenol, 1,1-bis(4-hydroxy-phenyl)ethane and 4,4'-dihydroxydiphenylsulfone. For a better correlation between chemical structure and thermal stability, molecular simulations were performed, using the HYPERCHEM (version 4.5) program. The lowest thermal stability was exhibited by the polymers that contain azobenzene units. The best thermal stability was that of the polyethers containing thiodiphenyl and 1,1-bis(phenyl)ethane units.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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