Authors:
E. Collar Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Departamento de Física e Ingeniería de Polímeros Juan de la Cierva 3 28006 Madrid Spain Juan de la Cierva 3 28006 Madrid Spain

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C. Marco Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Departamento de Física e Ingeniería de Polímeros Juan de la Cierva 3 28006 Madrid Spain Juan de la Cierva 3 28006 Madrid Spain

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O. Laguna Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Departamento de Física e Ingeniería de Polímeros Juan de la Cierva 3 28006 Madrid Spain Juan de la Cierva 3 28006 Madrid Spain

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S. Areso Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Departamento de Física e Ingeniería de Polímeros Juan de la Cierva 3 28006 Madrid Spain Juan de la Cierva 3 28006 Madrid Spain

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J. García-Martínez Instituto de Ciencia y Tecnología de Polímeros, C.S.I.C. Departamento de Física e Ingeniería de Polímeros Juan de la Cierva 3 28006 Madrid Spain Juan de la Cierva 3 28006 Madrid Spain

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Abstract  

A discussion on the influence of grafted polar groups (succinic anhydride and succinil-fluorescein) in glass transition behaviour of atactic polypropylene is shown in this work, on the basis of the reaction conditions used to obtain the modified polymers, kind and amount of grafted groups, and the degradation processes which may take place. The Box-Wilson experimental design methodology for two independent variables (reactant concentration to obtain the modified polymer) has been used to follow variations in glass transition temperatures. The existence of undesired degradation processes is considered as independent of the grafting reactions, and the model predictions seem to agree with this latter.

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation
1969
Volumes
per Year
1
Issues
per Year
24
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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