Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 58: Issue 3
Thermal Analysis of Fe(III) Complexes with Salicylaldehyde Semi-, Thiosemi- and S-methylisothiosemi-carbazones
Authors:
A. Petrović Institute of Physics Faculty of Sciences Trg D. Obradovića 4 21000 Novi Sad Yugoslavia Trg D. Obradovića 4 21000 Novi Sad Yugoslavia

Search for other papers by A. Petrović in
Current site
Google Scholar
PubMed Close
,
D. Petrović Institute of Physics Faculty of Sciences Trg D. Obradovića 4 21000 Novi Sad Yugoslavia Trg D. Obradovića 4 21000 Novi Sad Yugoslavia

Search for other papers by D. Petrović in
Current site
Google Scholar
PubMed Close
,
V. Leovac Institute of Chemistry Faculty of Sciences 21000 Novi Sad Yugoslavia 21000 Novi Sad Yugoslavia

Search for other papers by V. Leovac in
Current site
Google Scholar
PubMed Close
, and
M. Budimir Technical Faculty 19210 Bor Yugoslavia 19210 Bor Yugoslavia

Search for other papers by M. Budimir in
Current site
Google Scholar
PubMed Close
Pages:
589–596
Online Publication Date:
03 Nov 2004
Publication Date:
25 Dec 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010100427217
Restricted access

Abstract  

The paper describes the results of differential thermal analysis of the octahedral Fe(III) complexes of the general formula [Fe(HLn)2]Cl and Fe(HL3)L3, as well as of the corresponding ligands H2Ln (H2Ln — tridentate salicylaldehyde semi thiosemi- and S-methylisothiosemi-carabazones with n=1, 2 and 3 respectively). The decomposition of the complexes involving sulphur-containing ligands (H2L2 and H2L3) starts with sulphur elimination. In case of the complexes [Fe(HL2)]Cl and [Fe(HL3)]Cl sulphur evolves independently, whereas with Fe(HL3)L3 it is eliminated within the SCH3 group. In the former case, sulphur elimination takes place at the same temperature for both complexes. The change in the coordination mode, being a consequence of the replacement of O by S, has no essential effect on thermal stability of the coordination polyhedron. The complexes involving ONN coordination, realized with the H2L3 ligand, exhibit a comparatively highest thermal stability of the coordination polyhedron.

  • Collapse
  • Expand
Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

To see the editorial board, please visit the website of Springer Nature.

Manuscript Submission: HERE

For subscription options, please visit the website of Springer Nature.

Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Jun 2023 0 0 0
Jul 2023 0 0 0
Aug 2023 4 0 0
Sep 2023 1 0 1
Oct 2023 1 0 0
Nov 2023 2 1 0
Dec 2023 0 0 0