Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 58: Issue 3
Measurements of Heat of Zeolite Dehydration by Scanning Heating
Author:
V. Drebushchak Institute of Mineralogy and Petrography Universitetski Pr. 3 630090 Novosibirsk Russia Universitetski Pr. 3 630090 Novosibirsk Russia

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Pages:
653–662
Online Publication Date:
03 Nov 2004
Publication Date:
25 Dec 1999
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010116930852
Keywords:
dehydration; DSC; TG; water; zeolites
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Abstract  

A procedure for measurement of the heat of zeolite dehydration by scanning heating has been designed. Simultaneous data on heat flow (DSC) and mass loss (TG) are required for evaluation. The heating rate depends on the experimental conditions (point-spread function, sample mass, crucible design, and calorimetric reproducibility). Dehydration measurements have three advantages as compared with the sorption procedure: i) one can investigate samples with irreversible dehydration; ii) no approximation model is needed for calculation of the partial molar heat of dehydration; and iii) the procedure is not labor-consuming.The procedure was tested on the natural zeolites heulandite, chabazite and mordenite. The results are close to those measured by the sorption procedure. The partial molar heat of dehydration was found to depend on the water content. It increases from 50 to 87 J mol–1 K–1 for heulandite, from 53 to 81 J mol–1 K–1 for chabazite, and from 51 to 71 J mol–1 K–1 for mordenite.The approximation of the heat of sorption by linear regression was found to be wrong. Detection of a phase transitioN after this approximation has no meaning.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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