Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 59: Issue 1-2
Structure and Morphology of a Polyether/Polyacrylate Semi-interpenetrating Polymer Network
Authors:
F. Schilling Lucent Technologies Bell Laboratories Murray Hill NJ 07974 USA Murray Hill NJ 07974 USA

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H. Katz Lucent Technologies Bell Laboratories Murray Hill NJ 07974 USA Murray Hill NJ 07974 USA

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H. Bair Lucent Technologies Bell Laboratories Murray Hill NJ 07974 USA Murray Hill NJ 07974 USA

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Pages:
83–92
Online Publication Date:
02 Nov 2004
Publication Date:
25 Jan 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010123610324
Keywords:
cationic and photoinitiated polymerization; DSC; interfacial mixing; interpenetrating polymer network (IPN); glass transition temperature; NMR; quantitative thermal analysis of phases; reactive epoxy and acrylate systems; Tg broadening
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Abstract  

In this study NMR and DSC are used to probe the structure, thermal characteristics and morphology of a network formed from a diepoxide/acrylate system. Separate chemistries are employed to polymerize the diepoxide and acrylate components. The cationic polymerization of the diepoxide exhibits excellent selectivity in producing a crosslinked polyether network without affecting the acrylate monomer. Subsequent photoinitiated free-radical polymerization of the acrylate produces a phase separated, semi-interpenetrating polymer network (SIPN).

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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