Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 59: Issue 3
Kinetic and Thermodynamic Studies of Facial and Meridional uns-cis-[Co(eddp)gly] Complexes
Authors:
N. Petranović University of Belgrade Faculty of Physical Chemistry P.O. Box 173 11000 Belgrade Yugoslavia P.O. Box 173 11000 Belgrade Yugoslavia

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D. Minić University of Belgrade Faculty of Physical Chemistry P.O. Box 173 11000 Belgrade Yugoslavia P.O. Box 173 11000 Belgrade Yugoslavia

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T. Sabo University of Belgrade Faculty of Chemistry P.O. Box 158 11000 Belgrade Yugoslavia P.O. Box 158 11000 Belgrade Yugoslavia

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D. Doković University of Belgrade Faculty of Chemistry P.O. Box 158 11000 Belgrade Yugoslavia P.O. Box 158 11000 Belgrade Yugoslavia

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Pages:
807–814
Online Publication Date:
02 Nov 2004
Publication Date:
01 Mar 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010157821694
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Abstract  

Thermal properties of facial and meridional uns-cis-[Co(eddp)gly]0.5H2O complexes were investigated by means of DSC and TG techniques. It wasshown that the processes of thermal decomposition of these complexes are multi-stepdegradation processes, which can also be well separated into individual steps, depending onthe molecular symmetry. Thus, the process of thermal degradation of the meridional isomerof the above complex consists of 4 well-separated steps in the temperature interval from 100to 500C. The corresponding kinetic and thermodynamic parameters of this process weredetermined, and a possible mechanism is discussed.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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