Journal of Thermal Analysis and Calorimetry
Volume/Issue:
Volume 60: Issue 1
Mechanism of Thermal Decomposition of d-metals Nitrates Hydrates
Authors:
A. Małecki University of Mining and Metallurgy Faculty of Materials Science and Ceramics Al. Mickiewicza 30 30–059 Cracow Poland Al. Mickiewicza 30 30–059 Cracow Poland

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R. Gajerski University of Mining and Metallurgy Faculty of Materials Science and Ceramics Al. Mickiewicza 30 30–059 Cracow Poland Al. Mickiewicza 30 30–059 Cracow Poland

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S. Łabuś University of Mining and Metallurgy Faculty of Materials Science and Ceramics Al. Mickiewicza 30 30–059 Cracow Poland Al. Mickiewicza 30 30–059 Cracow Poland

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B. Prochowska-Klisch University of Mining and Metallurgy Faculty of Materials Science and Ceramics Al. Mickiewicza 30 30–059 Cracow Poland Al. Mickiewicza 30 30–059 Cracow Poland

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K. Wojciechowski University of Mining and Metallurgy Faculty of Materials Science and Ceramics Al. Mickiewicza 30 30–059 Cracow Poland Al. Mickiewicza 30 30–059 Cracow Poland

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Pages:
17–23
Online Publication Date:
02 Nov 2004
Publication Date:
01 Apr 2000
Article Category:
Research Article
DOI:
https://doi.org/10.1023/a:1010155931266
Keywords:
DTA; EGA; d-metals; nitrates; thermal decomposition
Restricted access

Abstract  

A series of six nitrates(V) hydrates of 4d-metals as well as mercury and cadmium thermal decomposition was examined by DTA, TG and EGA techniques. It was found that thermal decomposition of d-metals nitrate(V) hydrates proceeds in three stages: partial dehydration, oxo-nitrates and hydroxide nitrates formation and metal oxides formation. General chemical equations for all decomposition stages were proposed. It was found that dehydration of hydrated salts is accompanied by partial decomposition of nitrate(V) groups.

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Cover Journal of Thermal Analysis and Calorimetry
Journal of Thermal Analysis and Calorimetry
Print ISSN:
1388-6150
Online ISSN:
1572-8943

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Journal of Thermal Analysis and Calorimetry
Language English
Size A4
Year of
Foundation		 1969
Volumes
per Year		 1
Issues
per Year		 24
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1388-6150 (Print)
ISSN 1588-2926 (Online)

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